Single crystals of copper lead triantimony hexaselenide, CuPbSb 3Se6, were obtained as a minor phase during systematic studies of the formation conditions of selenide-based sulfosalts. The crystal structure is an unusual representative of the family of sulfosalts. Instead of the expected galena-like slabs with octahedral coordination, it features mono and double-capped trigonal–prismatic (Pb), square-pyramidal (Sb) and trigonal–bipyramidal (Cu) coordination. All metal positions are occupationally and/or positionally disordered.
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