Record link: 
http://hdl.handle.net/20.500.12708/162139
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Title: 
New Zn complexes based on 1,2,4-triazoles: synthesis, structure and luminescence
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Citation: 
Gusev, A. N., Shul’gin, V. F., Konnic, O. V., Meshkova, S. B., Aleksandrov, G. G., Kiskin, M. A., Eremenko, I. L., & Linert, W. (2011). New Zn complexes based on 1,2,4-triazoles: synthesis, structure and luminescence. Inorganica Chimica Acta, 376(1), 509–514. https://doi.org/10.1016/j.ica.2011.07.009
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Publisher DOI: 
10.1016/j.ica.2011.07.009
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Publication Type: 
Article - Original Research Article
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Language: 
English
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Authors: 
Gusev, Alexey N. 
Shul’gin, Victor F. 
Konnic, Oleg V. 
Meshkova, Svetlana B. 
Aleksandrov, Grygory G. 
Kiskin, Mikhail A. 
Eremenko, Igor L. 
Linert, Wolfgang 
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Organisational Unit: 
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie 
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Journal: 
Inorganica Chimica Acta 
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ISSN: 
0020-1693
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Date (published): 
1-Oct-2011
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Number of Pages: 
6
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Publisher: 
ELSEVIER SCIENCE SA
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Peer reviewed: 
Yes
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Keywords: 
Inorganic Chemistry; Physical and Theoretical Chemistry; Materials Chemistry; 2; 1; 4-triazole; X-ray study; zinc complexes; luminescence.
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Abstract: 
The reaction of 3-(pyridin-2-yl)-5-(2-aminophenyl)-1H-1,2,4-triazole and salicylaldehyde or benzaldehyde leads a new type of 1,2,4-triazole's derivats. Reactions of these ligands with zinc acetate in ethanol lead to the formation of two new complexes with azomethine or dihydrotriazaindolizine form of ligands. The structures of these complexes were investigated by X-ray analysis. The complexes showed strong green-blue luminescence in solid state.
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Research Areas: 
Structure-Property Relationship: 100%
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Science Branch: 
Chemie
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