Record link: 
http://hdl.handle.net/20.500.12708/166866
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Title: 
Studies on the Formation of CdS Nanoparticles from Solutions of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆]
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Citation: 
Bendova, M., Puchberger, M., Pabisch, S., Peterlik, H., & Schubert, U. (2010). Studies on the Formation of CdS Nanoparticles from Solutions of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆]. European Journal of Inorganic Chemistry, 2010(15), 2266–2275. https://doi.org/10.1002/ejic.201000080
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Publisher DOI: 
10.1002/ejic.201000080
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Publication Type: 
Article - Original Research Article
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Language: 
English
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Authors: 
Bendova, Maria 
Puchberger, Michael 
Pabisch, Silvia 
Peterlik, Herwig 
Schubert, Ulrich 
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Organisational Unit: 
E165-02 - Forschungsbereich Molekulare Materialchemie 
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Journal: 
European Journal of Inorganic Chemistry 
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ISSN: 
1434-1948
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Date (published): 
2010
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Number of Pages: 
10
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Publisher: 
WILEY-V C H VERLAG GMBH
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Peer reviewed: 
Yes
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Keywords: 
Inorganic Chemistry
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Abstract: 
The stepwise cluster growth, and formation of CdS nanoparticles from solutions of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆] in dimethyl sulfoxide (DMSO), dimethylformamide (DMF) and acetonitrile was investigated. Cluster growth is fast in DMSO and DMF at room temperature, and slow in acetonitrile at elevated temperatures. Larger sulfide clusters (initially Cd₃₂, then Cd₅₄) are initially formed, which upon further growth eventually give rise to CdS nanoparticles. Strong evidence was found that the byproduct formed during the reaction in DMSO is mononuclear [Cd(SPh)ₓ(DMSO)ᵧ]⁽²⁻ˣ⁾(x~3).
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Project title: 
Polymers from functional clusters (Fonds zur Förderung der wissenschaftlichen Forschung (FWF)) 
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Research Areas: 
Special and Engineering Materials: 10%
Surfaces and Interfaces: 90%
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Science Branch: 
Chemie
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