Schnürch, M. (2023). Exploiting charged groups for metal-catalyzed meta-C–H functionalization of arenes. Chem, 9(4), 764–766. https://doi.org/10.1016/j.chempr.2023.03.013
E163 - Institut für Angewandte Synthesechemie E163-03 - Forschungsbereich Organische und Biologische Chemie E163-03-4 - Forschungsgruppe Bioorganische Synthesechemie
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Zeitschrift:
Chem
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ISSN:
2451-9294
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Datum (veröffentlicht):
13-Apr-2023
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Umfang:
3
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Verlag:
CELL PRESS
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Peer Reviewed:
Nein
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Keywords:
C-H Activation
en
Abstract:
Direct meta-functionalization of C–H bonds in arene systems is a more challenging topic than ortho-functionalization. In this issue of Chem, the van Gemmeren and Maiti groups independently report on a new approach that relies on substrate-ligand interactions between charged groups rather than coordination of the metal center to a directing group, avoiding large and complex covalently bound directing groups.
