Huber, M., Schöbinger, M., Mundigler, S., Schnizer, J., Stöger, B., & Weinberger, P. (2024, July 13). The new class of fluorescent iron(II) spin crossover compounds based on BODIPY-substituted tetrazoles [Conference Presentation]. Spin States & Light, Jena, Germany. http://hdl.handle.net/20.500.12708/199532
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie E057-04 - Fachbereich Röntgenzentrum
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Datum (veröffentlicht):
13-Jul-2024
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Veranstaltungsname:
Spin States & Light
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Veranstaltungszeitraum:
12-Jul-2024 - 13-Jul-2024
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Veranstaltungsort:
Jena, Deutschland
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Keywords:
iron(II) spin crossover; BODIPY; luminescence
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Abstract:
In this paper, we present the synthetic pathway for the preparation of a new class of BODIPY-substituted tetrazoles using the previous presented omega-(1H-tetrazol-1-yl) carboxylic acids as precursors. This allows for the preparation of fluorescent tetrazole ligands combining the well-known fluorescent 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) moiety with the coordinating tetrazole moiety. Upon complexation the new fluorescent iron(II) spin crossover complex [Fe(2TzBODIPY)4(MeCN)2](ClO4)2 was prepared.
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Forschungsinfrastruktur:
Röntgenzentrum Zentrum für Kernspinresonanzspektroskopie
