High-field ultrasound study of elastic constants and possible magnetic symmetry transformations in UO₂

Abstract

In this study, we probe the coupling between magnetism and lattice dynamics in UO2, a 3k antiferromagnet that undergoes magnetic ordering below its Néel temperature (TN) of 30.8 K. Ultrasound measurements provide insights into the interplay between the material's magnetic properties and lattice vibrations in response to the applied high magnetic field. A model analysis based on ab initio calculated superexchange interactions predicts a change in the magnetic structure from 3k to 2k at around 50 T. Although this change is not evident in the magnetization curve, we observe a crossover of ultrasound velocity Δv/v using a phase-sensitive pulse-echo technique in pulsed magnetic fields of up to 65 T. We show that at Hz > 50 T, the structure remains antiferromagnetic in the xy plane and becomes ferromagnetic in the z direction. A further transition into the 1k structure is theoretically predicted to take place at a magnetic field of ∼104T.