A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada–Corriu and Negishi cross-coupling reactions

Mastalir, Mathias; Kirchner, Karl

doi:10.1007/s00706-016-1878-4

Record link:

https://resolver.obvsg.at/urn:nbn:at:at-ubtuw:3-2727
http://hdl.handle.net/20.500.12708/325

Title:

A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada–Corriu and Negishi cross-coupling reactions

Citation:

Mastalir, M., & Kirchner, K. (2017). A triazine-based Ni(II) PNP pincer complex as catalyst for Kumada–Corriu and Negishi cross-coupling reactions. Monatshefte Für Chemie - Chemical Monthly. https://doi.org/10.1007/s00706-016-1878-4

Publisher DOI:

10.1007/s00706-016-1878-4

CatalogPlus:

AC11361198

Publication Type:

Article - Original Research Article

Language:

English

Authors:

Mastalir, Mathias
Kirchner, Karl

Organisational Unit:

E163 - Institut für Angewandte Synthesechemie

Journal:

Monatshefte für Chemie - Chemical Monthly

ISSN:

0026-9247

Date (published):

Jan-2017

Publisher:

Springer

Peer reviewed:

Yes

Keywords:

Metal complexes; Pincer ligands; Homogeneous catalysis; Cross-coupling; Nickel

Abstract:

Kumada–Corriu and Negishi cross-coupling reactions, catalyzed efficiently by a Ni(II) PNP pincer complex containing a triazine backbone, are described. The catalyst is able to react with both activated and inactivated aryl halides including chlorides as well as phenol derivatives such as tosylates and mesylates to give the corresponding cross-coupling products in good to excellent isolated yields. A high diversity of substrates was tested under moderate conditions for both types of reactions.

License:

CC BY 4.0