An iron(II) complex featuring κ3 and labile κ2-bound PNP pincer ligands - striking differences between CH2 and NH spacers

Bichler, Bernhard; Glatz, Mathias; Stöger, Berthold; Mereiter, Kurt; Veiros, Luis F.; Kirchner, Karl

doi:10.1039/C4DT01933D

Record link:

https://resolver.obvsg.at/urn:nbn:at:at-ubtuw:3-2059
http://hdl.handle.net/20.500.12708/157

Title:

An iron(II) complex featuring κ3 and labile κ2-bound PNP pincer ligands - striking differences between CH2 and NH spacers

Citation:

Bichler, B., Glatz, M., Stöger, B., Mereiter, K., Veiros, L. F., & Kirchner, K. (2014). An iron(II) complex featuring κ3 and labile κ2-bound PNP pincer ligands - striking differences between CH2 and NH spacers. Dalton Transactions. https://doi.org/10.1039/C4DT01933D

Publisher DOI:

10.1039/C4DT01933D

CatalogPlus:

AC11360216

Publication Type:

Article - Short/Brief/Rapid Communication

Language:

English

Authors:

Bichler, Bernhard
Glatz, Mathias
Stöger, Berthold
Mereiter, Kurt
Veiros, Luis F.
Kirchner, Karl

Organisational Unit:

E163 - Institut für Angewandte Synthesechemie

Journal:

Dalton Transactions

ISSN:

1477-9226

Date (published):

21-Oct-2014

Publisher:

Royal Society of Chemistry

Peer reviewed:

Yes

Abstract:

Treatment of anhydrous FeCl2 with 2 equiv. of the pincer ligand PNP-Ph afforded the diamagnetic cationic octahedral complex [Fe(κ3-P,N,P-PNP)(κ2-P,N-PNP)Cl]+ featuring a κ2-P,N-bound PNP ligand. Preliminary reactivity studies revealed that the κ2-P,N-bound PNP ligand is labile reacting with CO to afford trans-[Fe(PNP-Ph)(CO)2Cl]+.

Additional information:

The final publication is available at <a href="https://doi.org/10.1039/C4DT01933D">https://doi.org/10.1039/C4DT01933D</a>.

License:

In Copyright

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