Dual sorbent coating based magnet-integrated fabric phase sorptive extraction as a front-end to gas chromatography-mass spectrometry for multi-class pesticide determination in water samples

Abstract

Magnet-integrated fabric phase sorptive extraction (MI-FPSE) is a sample preparation technique that has proved to be a powerful tool for environmental analysis. The fabrication and application of magnet-integrated dual sorbent-based FPSE membrane prepared by combining two different sol-gel sorbent-coated disks of different polarities together with a magnetic bar inserted between the two membranes to allow the stirring, was examined as novel preparation technique that not required samples pretreatments. The dual sorbent-based sample preparation platforms (made up of poly(tetrahydrofuran) and Carbowax 20M) were used for the extraction of seven classes of pesticides from ambient surface water samples prior to their determination by gas chromatography-mass spectrometry. Initially, different single and dual sol-gel sorbent-based MI-FPSE membranes were evaluated in terms of their extraction efficiency. The MI-FPSE with dual sol-gel sorbents were found to be superior to the single-materials MI-FPSE devices in terms of extraction recovery. The main parameters affecting the MI-FPSE extraction protocol (e.g., adsorption time, sample volume, stirring rate, salt addition, eluent type, desorption time and elution volume) were investigated. The selected extraction protocol enabled detection limits in the range between 0.001 and 0.16 ng mL-1. Furthermore, good relative standard deviation values for the intra-day and inter-day repeatability studies were obtained and were lower than 5.9 and 9.9 %, respectively. The proposed method was successfully used for the multi-class analysis of environmental surface water samples.