Glöcklhofer, F., Morawietz, A. J.-A., Stöger, B., Unterlass, M. M., & Fröhlich, J. (2017). Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility. ACS Omega, 2(4), 1594–1600. https://doi.org/10.1021/acsomega.7b00245
The preparation of cyanated acenes from quinones has been improved for the conversion of electron-poor starting materials. The new procedure was used to prepare rationally designed 2,7-dinitro-9,10-dicyanoanthracene. Crystallographic, morphological, and electrochemical investigations have revealed most promising properties for applications in organic electronics.
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