Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility

Glöcklhofer, Florian; Morawietz, Andreas Jong-An; Stöger, Berthold; Unterlass, Miriam Margarete; Fröhlich, Johannes

doi:10.1021/acsomega.7b00245

Record link:

http://hdl.handle.net/20.500.12708/19973

Title:

Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility

Citation:

Glöcklhofer, F., Morawietz, A. J.-A., Stöger, B., Unterlass, M. M., & Fröhlich, J. (2017). Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility. ACS Omega, 2(4), 1594–1600. https://doi.org/10.1021/acsomega.7b00245

Publisher DOI:

10.1021/acsomega.7b00245

Publication Type:

Article - Original Research Article

Language:

English

Authors:

Glöcklhofer, Florian
Morawietz, Andreas Jong-An
Stöger, Berthold
Unterlass, Miriam Margarete
Fröhlich, Johannes

Organisational Unit:

E163-03 - Forschungsbereich Organische und Biologische Chemie
E165 - Institut für Materialchemie

Journal:

ACS Omega

ISSN:

2470-1343

Date (published):

30-Apr-2017

Number of Pages:

Publisher:

AMER CHEMICAL SOC

Peer reviewed:

Yes

Keywords:

Hydrocarbons; solubility; catalyst; aromatic compound; crystal structure

Abstract:

The preparation of cyanated acenes from quinones has been improved for the conversion of electron-poor starting materials. The new procedure was used to prepare rationally designed 2,7-dinitro-9,10-dicyanoanthracene. Crystallographic, morphological, and electrochemical investigations have revealed most promising properties for applications in organic electronics.

Research facilities:

Universitäre Service-Einrichtung für Transmissionselektronenmikroskopie

License:

CC BY 4.0